Vinyl acetate | تولید کننده رزین |صنایع ایجاد رزین جام
(0) Cart
Заказать
  • ۲۹
    بهم

    Vinyl acetate

    http://si-resinjam.co.ir/en/vinyl-acetate.html
    posted in Science

    Vinyl acetate is an organic compound with the formula CH3CO2CHCH2. A colorless liquid with a pungent odor, it is the precursor to polyvinyl acetate, an important polymer in industry.

    Production
    The worldwide production capacity of vinyl acetate monomer (VAM) was estimated at 6,154,000 tonnes/annum in 2007, with most capacity concentrated in the United States (1,585,000 all in Texas), China (1,261,000), Japan (725,000) and Taiwan (650,000). The average list price for 2008 was $1600/tonne. Celanese is the largest producer (ca 25% of the worldwide capacity), while other significant producers include China Petrochemical Corporation (7%), Chang Chun Group (6%) and LyondellBasell (5%).

    It is a key ingredient in furniture-glue.

    Preparation
    The major industrial route involves the reaction of ethylene and acetic acid with oxygen in the presence of a palladium catalyst.

    C2H4 + CH3CO2H + 1/2 O2 → CH3CO2CHCH2 + H2O
    The main side reaction is the combustion of organic precursors. Vinyl acetate was once prepared by hydroesterification. This method involves the gas-phase addition of acetic acid to acetylene in the presence of metal catalysts. By this route, using mercury(II) catalysts, vinyl acetate was first prepared by Klatte in 1912. Another route to vinyl acetate involves thermal decomposition of ethylidene diacetate:

    (CH3CO2)2CHCH3 → CH3CO2CHCH2 + CH3CO2H

    Polymerization
    It can be polymerized to give polyvinyl acetate. With other monomers can be used to prepare copolymers such as ethylene-vinyl acetate (EVA), vinyl acetate-acrylic acid (VA/AA), polyvinyl chloride acetate (PVCA), and polyvinylpyrrolidone (Vp/Va Copolymer, used in hair gels).Due to the instability of the radical, attempts to control the polymerization via most ‘living/controlled’ radical processes have proved problematic. However, RAFT (or more specifically MADIX) polymerization offers a convenient method of controlling the synthesis of PVA by the addition of a xanthate or a dithiocarbamate chain transfer agent.

    Other reactions
    Vinyl acetate undergoes many of the reactions anticipated for an alkene and an ester. Bromine adds to give the dibromide. Hydrogen halides add to give 1-haloethyl acetates, which cannot be generated by other methods because of the non-availability of the corresponding halo-alcohols. Acetic acid adds in the presence of palladium catalysts to give ethylidene diacetate, CH3CH(OAc)2. It undergoes transesterification with a variety of carboxylic acids. The alkene also undergoes Diels-Alder and 2+2 cycloadditions.

    Toxicity evaluation
    On January 31, 2009, the Government of Canada’s final assessment concluded that exposure to vinyl acetate is not considered to be harmful to human health. This decision under the Canadian Environmental Protection Act (CEPA) was based on new information received during the public comment period, as well as more recent information from the risk assessment conducted by the European Union.

    Text for article taken from wikipedia.org.

ضمن خیر مقدم به سایت صنایع ایجاد رزین جام ، ما را از نظرات و پیشنهادات خود بهره مند فرمایید

0 comments

× You need to log in to enter the discussion